Browsing by Subject "manganese derivative"
Now showing items 1-9 of 9
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A hexameric [Mn III 18 Na6] wheel based on [Mn III 3 O]7+ sub-units
(2016)A novel hexameric [MnIII18Na6] wheel-like aggregate consisting of [MnIII3O] triangles is reported. It is the second highest nuclearity oxime-based Mn cluster, the largest member of the recently-developed family of molecular ...
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Inducing single-molecule magnetism in a family of loop-of-loops aggregates: Heterometallic Mn40Na4 clusters and the homometallic Mn44 analogue
(2010)The syntheses, crystal structures, and magnetic properties of a new family of heterometallic Mn40Na4 and homometallic Mn44 loop-of-loops aggregates are reported. The reactions of [Mn3O(O 2CMe)6(py)3]•py with 1,3-propanediol ...
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LaSrMnCoO6: A new cubic double perovskite oxide
(2003)Single-phase polycrystalline powder samples of the double perovskite oxide LaSrMnCoO6 were synthesized by the Pechini (citrate-gel) technique. The structural, magnetic and electrical properties of the obtained powders were ...
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Manganese citrate chemistry: Syntheses, spectroscopic studies, and structural characterizations of novel mononuclear, water-soluble manganese citrate complexes
(2000)The first two mononuclear manganese citrate complexes, (NH4)4[Mn(II)(C6H5O7)2] (1) and (NH4)5[Mn(III)(C6H4O7)2]·2H2O (2) were synthesized in aqueous solutions near physiological pH values. They were isolated in their pure ...
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Article
A novel aggregate of [Mn2(μ-O)2] units: [Mn8O10(O2CMe)6(H2O) 2(bpy)6]4+ with a serpentine core
(2003)The synthesis, characterization and initial reactivity studies are reported of the mixed-valence (MnIV 6MnIII 2) title compound, which possesses an unusual serpentine-like core and is the highest average oxidation state ...
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A reductive-aggregation route to [Mn12O12(OMe) 2(O2CPh)16(H2O)2] 2- single-molecule magnets related to the [Mn12] family
(2004)Axes of power: Jahn-Teller isomerism (that is, Jahn-Teller distortion along different axes) accounts for the presence of both faster and slower relaxing magnetization dynamics of the title compound (see core structure
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Symmetric and asymmetric dinuclear manganese(IV) complexes possessing a [MnIV2(μ-O)2(μ-O2 CME)3+ core and terminal Cl- ligands
(2003)The synthesis of new dinuclear manganese(IV) complexes possessing the [MnIV2(μ-O)2(μ-O2C Me)]3+ core and containing halide ions as terminal ligands is reported, [Mn2O2(O2CMe)Cl2 (bpy)2]2[MnCl4] (1
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Template Synthesis and Single-Molecule Magnetism Properties of a Complex with Spin S = 16 and a [Mn8O8]8+ Saddle-Like Core
(2003)The compound [CeIVMn8IIIO8(O2CMe)12(H2O)4]·4H2O (1·4H2O) has been obtained from a template synthesis involving the reaction of the chain polymer {[MnIII(OH)(O2CMe)2]·(MeCO2H)·(H2O)}n (3) with Ce(IV). Compound 1 contains a ...
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Article
Thickness dependence of Hall transport in Ni1.15Mn 0.85Sb thin films on silicon
(2004)Highly spin polarized Heusler alloys, NiMnSb and Co2MnSi, attract a great deal of interest as potential spin injectors for spintronic applications. Spintronic devices require control of interfacial properties at the ...